Recent progress in thick‐film organic photovoltaic devices:
Herein we summarize the recent progress in developing thick-film organic photovoltaic devices from the perspective of efficiency-loss mechanisms, material design, and device optimization
In this regard, it is of particular interests to develop OPV devices with increased active layer thickness (Figure 1B), as it can improve light-harvesting capability and, thus, theoretically enhance the short-current density (JSC), which simultaneously lead to more favorable compatibility with high-throughput roll-to-roll (R2R) processing.
However, the increase in film thickness of the light-harvesting layer may enhance the recombination probability of charge carriers and is unfavorable to charge extraction, which may lead to decreased photovoltaic parameters including JSC and fill factor (FF).
Theoretically, to achieve high JSC, the typical thickness of the photoactive layer is >200 nm to ensure effective harvest of solar photons. 11, 19, 20 However, increasing the thickness of a bulk heterojunction (BHJ) layer often degrades the photovoltaic performance in actual experiments.
To achieve efficient thickness-insensitive photovoltaic devices for the progression of lab-to-fab preparation, one needs to carefully optimize the device parameters to address the trade-off between light harvesting and charge transfer.
Herein we summarize the recent progress in developing thick-film organic photovoltaic devices from the perspective of efficiency-loss mechanisms, material design, and device optimization
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To enhance the photovoltaic properties of PSCs,several materials for the electron transport layer (ETL) have been investigated. Zinc oxide (ZnO) is a significant ETLdue to its high electron mobility and
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